Ferroelectric quantum criticality and enhanced superconductivity in plastically deformed strontium titanate

The properties of quantum materials are commonly tuned using experimental variables such as pressure, magnetic field and doping. Here we explore a different approach: irreversible, plastic deformation of single crystals. We show for the superconductor SrTiO₃ that compressive plastic deformation induces low-dimensional superconductivity significantly above the superconducting transition temperature (T_c) of undeformed samples, with evidence of possible superconducting correlations at temperatures two orders of magnitude above the bulk T_c. The superconductivity enhancement is correlated with the appearance of self-organized dislocation structures, as revealed by diffuse neutron and X-ray scattering. We also observe signatures of deformation-induced quantum-critical ferroelectric fluctuations and inhomogeneous ferroelectric order via Raman scattering. These results suggest that the strain surrounding the self-organized dislocation structures induces local ferroelectricity and quantum-critical dynamics that strongly influence T_c, consistent with a theory of superconductivity enhanced by soft polar fluctuations. More broadly, our results demonstrate the promise of plastic deformation and dislocation engineering as tools to manipulate electronic properties of quantum materials [1].

[1] S. Hameed, D. Pelc, Z. W. Anderson, A. Klein, R. J. Spieker, L. Yue, B. Das, J. Ramberger, M. Lukas, Y. Liu, M. J. Krogstad, R. Osborn, Y. Li, C. Leighton, R. M. Fernandes and M. Greven, arXiv:2005.00514 (2020)